Search results for "Transport phenomena"
showing 10 items of 31 documents
Multiphysical Modeling of Transport Phenomena During Laser Welding of Dissimilar Steels
2016
Abstract The success of new high-strength steels allows attaining equivalent performances with lower thicknesses and significant weight reduction. The welding of new couples of steel grades requires development and control of joining processes. Thanks to high precision and good flexibility, laser welding became one of the most used processes for joining of dissimilar welded blanks. The prediction of the local chemical composition in the weld formed between dissimilar steels in function of the welding parameters is essential because the dilution rate and the distribution of alloying elements in the melted zone determines the final tensile strength of the weld. The goal of the present study i…
Current‐voltage curves of bipolar membranes
1992
Bipolar membranes consist of a layered ion‐exchange structure composed of a cation selective membrane joined to an anion selective membrane. They are analogous to semiconductor p‐n devices as both of them present current‐voltage curves exhibiting similar rectification properties. In this article, we present some current‐voltage curves obtained for different bipolar membranes at several temperatures. The results can be interpreted in terms of a simple model for ion transport and field‐enhanced water dissociation previously developed. The mechanism responsible for water splitting is assumed to be a catalytic proton transfer reaction between the charged groups and the water at the membrane int…
Role of the reagents consumption in the chaotic dynamics of the Belousov-Zhabotitinsky oscillator in closed unstirred reactors
2010
Chemical oscillations generated by the Belousov–Zhabotinsky reaction in batch unstirred reactors, show a characteristic chaotic transient in their dynamical regime, which is generally found between two periodic regions. Chemical chaos starts and finishes by following a direct and an inverse Ruelle–Takens–Newhouse scenario, respectively. In previous works we showed, both experimentally and theoretically, that the complex oscillations are generated by the coupling among the nonlinear kinetics and the transport phenomena, the latter due to concentration and density gradients. In particular, convection was found to play a fundamental role. In this paper, we develop a reaction–diffusion–convecti…
Chaotic dynamics in an unstirred ferroin catalyzed Belousov–Zhabotinsky reaction
2009
Abstract The Belousov–Zhabotinsky (BZ) reaction is the best known example of far from equilibrium self-organizing chemical reaction. Among the many dynamical behaviors that this reaction can exhibit, spatio-temporal chaos attracted particular interest, both for the ferroin and cerium catalyzed systems. In recent years transient chaos was found in the cerium catalyzed BZ reaction, when conducted in batch and unstirred reactors. It was established that the chaotic oscillations, originated by the coupling among chemical kinetics and transport phenomena, appeared and disappeared following a Ruelle–Takens–Newhouse scenario. In this Letter, we show results about the ferroin catalyzed system condu…
Anomalous transport effects on switching currents of graphene-based Josephson junctions
2017
We explore the effect of noise on the ballistic graphene-based small Josephson junctions in the framework of the resistively and capacitively shunted model. We use the non-sinusoidal current-phase relation specific for graphene layers partially covered by superconducting electrodes. The noise induced escapes from the metastable states, when the external bias current is ramped, give the switching current distribution, i.e. the probability distribution of the passages to finite voltage from the superconducting state as a function of the bias current, that is the information more promptly available in the experiments. We consider a noise source that is a mixture of two different types of proce…
Thermodynamics, transport phenomena, and electrochemistry of external field-assisted nonthermal food technologies
2017
Interest in the development and adoption of nonthermal technologies is burgeoning within the food and bioprocess industry, the associated research community, and among the consumers. This is evident from not only the success of some innovative nonthermal technologies at industrial scale, but also from the increasing number of publications dealing with these topics, a growing demand for foods processed by nonthermal technologies and use of natural ingredients. A notable feature of the nonthermal technologies such as cold plasma, electrohydrodynamic processing, pulsed electric fields, and ultrasound is the involvement of external fields, either electric or sound. Therefore, it merits to study…
Measurement of transport phenomena of volatile compounds: A review
2008
International audience; Measurement of the transport phenomena of volatile compounds is a central preoccupation in food flavour and is the subject of the present paper. After a theoretical reminder concerning transport phenomena, the methods used for the measurement of diffusion and mass transfer of volatile compounds are described with their principles, main advantages and drawbacks. These methods are illustrated by some results obtained for flavoured model food products.Several methods characterized by the type of diffusion coefficient measured, the method basis, the scale at which diffusion is measured and the means used to detect the diffusing molecule, are available to determine diffus…
A novel One Domain Approach for free fluid-porous medium transport simulation. Preliminary results
2022
We present a new numerical solver for free-fluid flowing over and inside a porous medium. It is based over a macroscopic approach and one fictitious medium is assumed inside the domain, according to the One Domain Approach. Preliminary results are shown and compared with the ones provided by the well-known DuMux solver which applies a two Domain Approach.
THE GOLDMAN CONSTANT FIELD ASSUMPTION - SIGNIFICANCE AND APPLICABILITY CONDITIONS
1986
Ionic transport phenomena in simple, porous membranes can be approximately represented by the Nernst-Planck flux equations and Poisson's equation. In order to solve this set of equations for each particular case, the Goldman constant field assumption is one of the most widely used. In the present paper the significance and the applicability conditions of the above hypothesis is critically examined. and the particular situations where it is exact are shown. These conditions are later verified by solving numerically the electrodiffusion equations. The analysis carried out shows that some of the earlier studies based on asymptotic expansions and numerical solutions should be partially revised.
Diffusion processes involving multiple conserved charges: a first study from kinetic theory and implications to the fluid-dynamical modeling of heavy…
2020
The bulk nuclear matter produced in heavy ion collisions carries a multitude of conserved quantum numbers: electric charge, baryon number, and strangeness. Therefore, the diffusion processes associated to these conserved charges cannot occur independently and must be described in terms of a set of coupled diffusion equations. This physics is implemented by replacing the traditional diffusion coefficients for each conserved charge by a diffusion coefficient matrix, which quantifies the coupling between the conserved quantum numbers. The diagonal coefficients of this matrix are the usual charge diffusion coefficients, while the off-diagonal entries describe the diffusive coupling of the charg…